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4,4′-Difluoro-[3,3′-bi(1,2,5-oxadiazole)] 2,2′-Dioxide Full article

Journal Molbank
ISSN: 1422-8599
Output data Year: 2023, Volume: 2023, Number: 1, Article number : M1596, Pages count : DOI: 10.3390/m1596
Authors Obruchnikova Natalia V. 1 , Rakitin Oleg A. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia

Abstract: 1,2,5-Oxadiazole oxides (furoxans) are well known nitric oxide donors; among them, 4-fluorofuroxans have recently been found to be important photoinduced nitric oxide donors. In this research, it was shown that the reaction of 4,4′-dinitro-[3,3′-bi(1,2,5-oxadiazole)] 2,2′-dioxide with fluoro-containing reagents (tetrabutylammonium fluoride or cesium fluoride) selectively gave the bis-substitution product 4,4′-difluoro-[3,3′-bi(1,2,5-oxadiazole)] 2,2′-dioxide. The structure of the synthesized compound was established by elemental analysis, 13C, 19F-NMR and IR spectroscopy, and mass-spectrometry.
Cite: Obruchnikova N.V. , Rakitin O.A.
4,4′-Difluoro-[3,3′-bi(1,2,5-oxadiazole)] 2,2′-Dioxide
Molbank. 2023. V.2023. N1. M1596 . DOI: 10.3390/m1596 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000958976300001
Scopus: 2-s2.0-85152263319
OpenAlex: W4321787279
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