35S Tracer study of the effect of support nature on the dynamics of the active sites of CoMo and NiMo sulfide catalysts supported on Al 2O3 and activated carbon Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 1608-3210 , E-ISSN: 0023-1584 |
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| Вых. Данные | Год: 2005, Том: 46, Номер: 1, Страницы: 77-87 Страниц : 11 DOI: 10.1007/s10975-005-0049-0 | ||
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Реферат:
The influence of the support (Al2O3 and activated carbon) on the activity of Mo, NiMo, and CoMo catalysts in thiophene hydrogenolysis is studied using 35S as a tracer. The carbon-supported catalysts have more active sites than their alumina-supported counterparts, while the turnover frequencies of these sites are similar. Thiophene desulfurization and hydrogenation of the resulting C4 olefins take place at the same Mo sites. Tracer tests have demonstrated that the active sites in the catalysts examined are identical and that the support has an effect only on their concentration.
Библиографическая ссылка:
Kogan V.M.
35S Tracer study of the effect of support nature on the dynamics of the active sites of CoMo and NiMo sulfide catalysts supported on Al 2O3 and activated carbon
Kinetics and Catalysis. 2005. V.46. N1. P.77-87. DOI: 10.1007/s10975-005-0049-0 WOS OpenAlex
35S Tracer study of the effect of support nature on the dynamics of the active sites of CoMo and NiMo sulfide catalysts supported on Al 2O3 and activated carbon
Kinetics and Catalysis. 2005. V.46. N1. P.77-87. DOI: 10.1007/s10975-005-0049-0 WOS OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000227731700012 |
| OpenAlex: | W2018122511 |