New method for the synthesis and the mechanism of formation of 1,2-di-and 1,2,3-trialkyldiaziridines

New method for the synthesis and the mechanism of formation of 1,2-di-and 1,2,3-trialkyldiaziridines Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2006, Volume: 55, Number: 11, Pages: 2056-2060 Pages count : 5 DOI: 10.1007/s11172-006-0548-9

Authors

Kuznetsov V.V. ¹ , Ovchinnikova V.B. ² , Ananikov V.P. ¹ , Makhova N.N. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	Russian Scientific Center “Applied Chemistry”, 14 Dobrolyubova prosp., St. Petersburg, Russian Federation

A new simple approach to the synthesis of 1,2-di-and 1,2,3-trialkyldiaziridines has been developed based on direct chlorination of a mixture of the corresponding aldehyde and an excess of primary aliphatic amine in water. The mechanism of this reaction is proposed and confirmed by quantum chemical calculations at the density functional theory level.

Kuznetsov V.V. , Ovchinnikova V.B. , Ananikov V.P. , Makhova N.N.
New method for the synthesis and the mechanism of formation of 1,2-di-and 1,2,3-trialkyldiaziridines
Russian Chemical Bulletin. 2006. V.55. N11. P.2056-2060. DOI: 10.1007/s11172-006-0548-9 WOS Scopus OpenAlex

Web of science:	WOS:000245501600021
Scopus:	2-s2.0-34247101212
OpenAlex:	W2952958564

DB	Citing
OpenAlex	6
Scopus	5
Web of science	5