New organosiloxanes based on 1-vinyl-2-perfluoroalkoxy-2,3,3-trifluorocyclobutanes

New organosiloxanes based on 1-vinyl-2-perfluoroalkoxy-2,3,3-trifluorocyclobutanes Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2005, Volume: 54, Number: 5, Pages: 1250-1253 Pages count : 4 DOI: 10.1007/s11172-005-0389-y

Authors

Shamaev A.E. ¹ , Glazkov A.A. ¹ , Ignatenko A.V. ¹ , Sakharov A.M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

A new method for the synthesis of polyfluorinated compounds, viz., chlorosilanes with 2-perfluoroalkoxy-2,3,3-trifluorocyclobutane substituents containing different numbers of tetrafluoro(ethylene oxide) (CF2CF2O) n units (n = 3–6), was developed. The structures of siloxanes formed by the hydrolysis of these chlorosilanes were studied: the hydrolysis of monochlorosilanes affords disiloxanes and that of dichlorosilanes produces cyclotrisiloxanes, cyclotetrasiloxanes, and cyclic (the number of siloxane units >4) and linear polysiloxanes.

Shamaev A.E. , Glazkov A.A. , Ignatenko A.V. , Sakharov A.M.
New organosiloxanes based on 1-vinyl-2-perfluoroalkoxy-2,3,3-trifluorocyclobutanes
Russian Chemical Bulletin. 2005. V.54. N5. P.1250-1253. DOI: 10.1007/s11172-005-0389-y WOS Scopus OpenAlex

≡ Web of science:	WOS:000233758600028
≡ Scopus:	2-s2.0-28444483596
≡ OpenAlex:	W2040909452