Transformations of cyclohexane and benzene on the bimetallic Ru-Pt oxide catalysts

Transformations of cyclohexane and benzene on the bimetallic Ru-Pt oxide catalysts Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2006, Volume: 55, Number: 4, Pages: 656-660 Pages count : 5 DOI: 10.1007/s11172-006-0308-x

Authors

Masloboishchikova O.V. ¹ , Khelkovskaya-Sergeeva E.G. ¹ , Bogdan V.I. ¹ , Vasina T.V. ¹ , Kustov L.M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

The bimetallic Ru-Pt/Al2O3 catalysts with an overall metal content of 1 wt. % and Pt: Ru weight ratios from 1: 3 to 3: 1 were studied. The catalytic activity for cyclohexane and benzene transformations, including hydrogenation, hydrogenolysis, and skeletal isomerization of the initial substrates and products of intermediate transformations, was studied at temperatures 180–350 °C and H2 pressures from 1.0 to 5.0 MPa. The maximum yield of n-hexane from cyclohexane and benzene was obtained on the catalysts with a ruthenium content of 0.75–1.0%, being ∼29–30 wt.% at 40% selectivity. The selectivity to form n-hexane decreases with an increase in the cyclohexane conversion and is almost independent of the composition of the Ru-Pt system. On the catalysts under study, benzene is converted to the same products but at temperatures by 60 °C lower as compared to cyclohexane conversion.

Masloboishchikova O.V. , Khelkovskaya-Sergeeva E.G. , Bogdan V.I. , Vasina T.V. , Kustov L.M.
Transformations of cyclohexane and benzene on the bimetallic Ru-Pt oxide catalysts
Russian Chemical Bulletin. 2006. V.55. N4. P.656-660. DOI: 10.1007/s11172-006-0308-x WOS Scopus OpenAlex

≡ Web of science:	WOS:000240812400007
≡ Scopus:	2-s2.0-33748551678
≡ OpenAlex:	W1985471783