A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes

A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 2003, Volume: 44, Number: 39, Pages: 7359-7363 Pages count : 5 DOI: 10.1016/s0040-4039(03)01844-6

Authors

Terent'ev Alexander O. ¹ , Kutkin Alexander V. ¹ , Platonov Maxim M. ¹ , Ogibin Yuri N. ¹ , Nikishin Gennady I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Leninsky Prospect, 47, Russia

A reaction of cycloalkanone, alkanone and alkyl aryl ketone ketals with H2O2 catalyzed by boron trifluoride etherate and boron trifluoride–methanol complexes was studied. A new versatile method for the synthesis of bishydroperoxides and their derivatives, viz. 1,1′-dihydroperoxyperoxides and 1,2,4,5-tetraoxacyclohexanes, was developed based on this reaction.

Terent'ev A.O. , Kutkin A.V. , Platonov M.M. , Ogibin Y.N. , Nikishin G.I.
A new method for the synthesis of bishydroperoxides based on a reaction of ketals with hydrogen peroxide catalyzed by boron trifluoride complexes
Tetrahedron Letters. 2003. V.44. N39. P.7359-7363. DOI: 10.1016/s0040-4039(03)01844-6 WOS Scopus OpenAlex

≡ Web of science:	WOS:000185605200029
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