Transformations of β-Hydroxo-Substituted η3-Allyl Pd Complexes in Neutral and Weakly Acidic Solutions

Transformations of β-Hydroxo-Substituted η3-Allyl Pd Complexes in Neutral and Weakly Acidic Solutions Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2005, Volume: 31, Number: 10, Pages: 685-694 Pages count : 10 DOI: 10.1007/s11173-005-0156-5

Authors

Finashina E.D. ¹ , Kramareva N.V. ¹ , Evstigneeva E.M. ² , Flid V.R. ² , Belov A.P. ²

Affiliations

1	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	Lomonosov Academy of Fine Chemical Technology, pr. Vernadskogo 86, 117571, Russia

The oxidation of some β-hydroxo-substituted η3-allyl Pd complexes based on the simplest 1,3-dienes is studied by the 1H and 13C NMR methods in neutral and weakly acidic methods. The composition of the reaction products is determined by the nature of the oxidizing agent and the structure of allyl fragment. The method of selective oxidation of the β-carbon atom of the allyl ligand with the allyl-metal bond remaining unchanged is suggested.

Finashina E.D. , Kramareva N.V. , Evstigneeva E.M. , Flid V.R. , Belov A.P.
Transformations of β-Hydroxo-Substituted η3-Allyl Pd Complexes in Neutral and Weakly Acidic Solutions
Russian Journal of Coordination Chemistry. 2005. V.31. N10. P.685-694. DOI: 10.1007/s11173-005-0156-5 WOS Scopus OpenAlex

≡ Web of science:	WOS:000232900300001
≡ Scopus:	2-s2.0-27144548779
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