Electrocatalytic transformation of malononitrile and cycloalkylidenemalononitriles into spirotricyclic and spirotetracyclic compounds containing cyclopropane and pyrroline fragments

Electrocatalytic transformation of malononitrile and cycloalkylidenemalononitriles into spirotricyclic and spirotetracyclic compounds containing cyclopropane and pyrroline fragments Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2003, Volume: 52, Number: 10, Pages: 2241-2246 Pages count : 6 DOI: 10.1023/b:rucb.0000011885.10104.da

Authors

Elinson M.N. ¹ , Fedukovich S.K. ¹ , Zaimovskaya T.A. ² , Vereshchagin A.N. ¹ , Nikishin G.I. ¹

Affiliations

1	N.D.Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, Moscow, Russian Federation
2	A. V. Topchiev Institutute of Petrochemical Synthesis of the Russian Academy of Sciences, Moscow, Russian Federation

Electrolysis of cycloalkylidenemalononitriles and malononitrile in MeOH in an undivided cell in the presence of the NaBr—NaOMe mediator system gives spirotricyclic compounds containing cyclopropane and pyrroline fragments in 50—77% yields. Spirobicyclic and spirotricyclic tetracyanocyclopropanes undergo electrolysis in alcohols to afford spirotricyclic and spirotetracyclic products containing cyclopropane and pyrroline fragments in 50—93% yields.

Elinson M.N. , Fedukovich S.K. , Zaimovskaya T.A. , Vereshchagin A.N. , Nikishin G.I.
Electrocatalytic transformation of malononitrile and cycloalkylidenemalononitriles into spirotricyclic and spirotetracyclic compounds containing cyclopropane and pyrroline fragments
Russian Chemical Bulletin. 2003. V.52. N10. P.2241-2246. DOI: 10.1023/b:rucb.0000011885.10104.da Scopus Scopus OpenAlex

Scopus:	2-s2.0-3543087502 \| 2-s2.0-3543061797
OpenAlex:	W2952776732

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