Baeyer–Villiger rearrangement of polyalkoxybenzaldehydes with benzene ring opening

Baeyer–Villiger rearrangement of polyalkoxybenzaldehydes with benzene ring opening Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2024, Volume: 34, Number: 3, Pages: 396-397 Pages count : 2 DOI: 10.1016/j.mencom.2024.04.026

Authors

Tsyganov Dmitry V. ¹ , Samigullina Aida I. ¹ , Semenov Victor V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The Baeyer–Villiger oxidation of apiolaldehyde bearing o-(3-p-anisylisoxazolin-5-yl)methyl substituent proceeds first with the formation of the anticipated phenol. The subsequent oxidation of phenol with destruction of methylenedioxy ring leads to p-quinone derivative which would undergo opening of the benzene ring to finally produce maleic anhydride moiety. The structure of new compounds was proved by X-ray diffraction analysis.

Tsyganov D.V. , Samigullina A.I. , Semenov V.V.
Baeyer–Villiger rearrangement of polyalkoxybenzaldehydes with benzene ring opening
Mendeleev Communications. 2024. V.34. N3. P.396-397. DOI: 10.1016/j.mencom.2024.04.026 WOS Scopus OpenAlex

Web of science:	WOS:001246346500001
Scopus:	2-s2.0-85194156313
OpenAlex:	W4399056903

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OpenAlex	1
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