Stereo- and Regioselective Functionalization of Alkynes Catalyzed by Platinum(IV) and Palladium(II) Complexes in the System I--I3--H2O/MeOH

Stereo- and Regioselective Functionalization of Alkynes Catalyzed by Platinum(IV) and Palladium(II) Complexes in the System I--I3--H2O/MeOH Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1608-3393 , E-ISSN: 1070-4280

Output data

Year: 2002, Volume: 38, Number: 5, Pages: 636-650 Pages count : 15 DOI: 10.1023/a:1019646619165

Authors

Ananikov V.P. ¹ , Mitchenko S.A. ² , Beletskaya I.P. ³

Affiliations

1	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, Moscow, Russia
3	Department of Chemistry, Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

Activation of the CÍÄC bond in acetylenic hydrocarbons, catalyzed by iodide complexes of platinum(IV), and the subsequent CÄC coupling reaction make it possible to synthesize 1,4-diiodo-substituted dienes with high stereo- and regioselectivity. The reaction involves intermediate formation of bis-σ-vinyl platinum(IV) complexes which can be isolated in the pure state. Under similar conditions palladium(II) complexes catalyze iodine addition to acetylene.

Ananikov V.P. , Mitchenko S.A. , Beletskaya I.P.
Stereo- and Regioselective Functionalization of Alkynes Catalyzed by Platinum(IV) and Palladium(II) Complexes in the System I--I3--H2O/MeOH
Russian Journal of Organic Chemistry. 2002. V.38. N5. P.636-650. DOI: 10.1023/a:1019646619165 Scopus OpenAlex

Scopus:	2-s2.0-0036344289
OpenAlex:	W2951894147

DB	Citing
OpenAlex	15
Scopus	19