Electrosynthesis of esters of mono- and dioxoalkanoic and alkanedioic acids on the basis of nitro-substituted alkyl carboxylates and cycloalkanones

Electrosynthesis of esters of mono- and dioxoalkanoic and alkanedioic acids on the basis of nitro-substituted alkyl carboxylates and cycloalkanones Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2003, Volume: 52, Number: 3, Pages: 728-733 Pages count : 6 DOI: 10.1023/a:1023935629115

Authors

Ogibin Yu.N. ¹ , Ilovaiskii A.I. ¹ , Merkulova V.M. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

A one-pot electrochemical method for the synthesis of methyl monooxoalkanoates with the carbonyl group in position 4, methyl dioxoalkanoates with the oxo groups in positions 4,7-, 6,9-, 7,10-, and 12,15, and methyl 4-oxoalkanedioates was developed. This method is based on amperostatic electrolysis in an undivided cell of the salts of esters of nitroalkaniic acids and their adducts with CH2=CHX (X = Ac, CO2Me).

Ogibin Y.N. , Ilovaiskii A.I. , Merkulova V.M. , Nikishin G.I.
Electrosynthesis of esters of mono- and dioxoalkanoic and alkanedioic acids on the basis of nitro-substituted alkyl carboxylates and cycloalkanones
Russian Chemical Bulletin. 2003. V.52. N3. P.728-733. DOI: 10.1023/a:1023935629115 WOS Scopus OpenAlex

Web of science:	WOS:000183739500032
Scopus:	2-s2.0-0038323226
OpenAlex:	W2949702678

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Scopus	2
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