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Fischer–Tropsch Synthesis Catalysts for Selective Production of Diesel Fraction Full article

Journal Catalysts
ISSN: 2073-4344
Output data Year: 2023, Volume: 13, Number: 8, Article number : 1215, Pages count : DOI: 10.3390/catal13081215
Authors Mazurova Kristina 1 , Miyassarova Albina 1 , Eliseev Oleg 2,3 , Stytsenko Valentine 1 , Glotov Aleksandr 1 , Stavitskaya Anna 1
Affiliations
1 Department of Physical and Colloid Chemistry, Gubkin University, 65 Lelinsky Prospect, Moscow 119991, Russia
2 Institute of Organic Chemistry, Peoples’ Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St., Moscow 117198, Russia
3 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences (RAS), 47 Lelinsky Prospect, Moscow 119991, Russia

Abstract: The Fischer–Tropsch process is considered one of the most promising eco-friendly routes for obtaining synthetic motor fuels. Fischer–Tropsch synthesis is a heterogeneous catalytic process in which a synthesis gas (CO/H2) transforms into a mixture of aliphatic hydrocarbons, mainly linear alkanes. Recently, an important direction has been to increase the selectivity of the process for the diesel fraction. Diesel fuel synthesized via the Fischer–Tropsch method has a number of advantages over conventional fuel, including the high cetane number, the low content of aromatic, and the practically absent sulfur and nitrogen impurities. One of the possible ways to obtain a high yield of diesel fuel via the Fischer–Tropsch process is the development of selective catalysts. In this review, the latest achievements in the field of production of diesel via Fischer–Tropsch synthesis using catalysts are reviewed for the first time. Catalytic systems based on Al2O3 and mesoporous silicates, such as MCM-41, SBA-15, and micro- and mesoporous zeolites, are observed. Together with catalytic systems, the main factors that influence diesel fuel selectivity such as temperature, pressure, CO:H2 ratio, active metal particle size, and carrier pore size are highlighted. The motivation behind this work is due to the increasing need for alternative processes in diesel fuel production with a low sulfur content and better exploitation characteristics.
Cite: Mazurova K. , Miyassarova A. , Eliseev O. , Stytsenko V. , Glotov A. , Stavitskaya A.
Fischer–Tropsch Synthesis Catalysts for Selective Production of Diesel Fraction
Catalysts. 2023. V.13. N8. 1215 . DOI: 10.3390/catal13081215 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:001056241200001
Scopus: 2-s2.0-85169119386
OpenAlex: W4385878234
Citing:
DB Citing
OpenAlex 25
Scopus 21
Web of science 18
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