A new method for synthesis of n-(3-acyloxypropyl)-substituted six- to thirteen-membered alkan-n-olides Научная публикация
| Журнал |
Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Вых. Данные | Год: 2002, Том: 51, Номер: 10, Страницы: 1806-1811 Страниц : 6 DOI: 10.1023/a:1021336031371 | ||
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Реферат:
A new method for the synthesis of n-(3-acyloxypropyl)-substituted six- to thirteen-membered alkan-n-olides was developed. The method is based on the H2SO4-catalyzed reactions of oxabicycloalkenes, obtained from 2-(3-acetoxypropyl)cycloalkanes, with H2O2 and formic or acetic acid. The method includes the subsequent transformations of oxabicycloalkenes into bicyclic hydroperoxides, peroxy ethers, and, at the final stage, into target lactones formed in 56—71% yields. These transformations are carried as a one-pot reaction.
Библиографическая ссылка:
Ogibin Y.N.
, Kutkin A.V.
, Terent"ev A.O.
, Nikishin G.I.
A new method for synthesis of n-(3-acyloxypropyl)-substituted six- to thirteen-membered alkan-n-olides
Russian Chemical Bulletin. 2002. V.51. N10. P.1806-1811. DOI: 10.1023/a:1021336031371 WOS Scopus OpenAlex
A new method for synthesis of n-(3-acyloxypropyl)-substituted six- to thirteen-membered alkan-n-olides
Russian Chemical Bulletin. 2002. V.51. N10. P.1806-1811. DOI: 10.1023/a:1021336031371 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000180430000004 |
| Scopus: | 2-s2.0-0036450883 |
| OpenAlex: | W2952735342 |