(2-Fluoroallyl)pyridinium tetrafluoroborates: novel fluorinated electrophiles for Pd-catalyzed allylic substitution

(2-Fluoroallyl)pyridinium tetrafluoroborates: novel fluorinated electrophiles for Pd-catalyzed allylic substitution Full article

Journal

Organic & Biomolecular Chemistry
ISSN: 1477-0520 , E-ISSN: 1477-0539

Output data

Year: 2021, Volume: 19, Number: 21, Pages: 4678-4684 Pages count : 7 DOI: 10.1039/d1ob00567g

Authors

Bobrova Angelina Yu. ^1,2 , Novikov Maxim A. ¹ , Tomilov Yury V. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation
2	Higher Chemical College of the Russian Academy of Sciences, D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047 Moscow, Russian Federation

An efficient two-step approach to 2-fluoroallyl amines was developed that involves the synthesis of (2-fluoroallyl)pyridinium tetrafluoroborates from readily available gem-bromofluorocyclopropanes and the application of the former as novel and stable 2-fluoroallyl electrophiles for Pd-catalyzed allylic substitution.

Bobrova A.Y. , Novikov M.A. , Tomilov Y.V.
(2-Fluoroallyl)pyridinium tetrafluoroborates: novel fluorinated electrophiles for Pd-catalyzed allylic substitution
Organic & Biomolecular Chemistry. 2021. V.19. N21. P.4678-4684. DOI: 10.1039/d1ob00567g WOS Scopus OpenAlex

≡ Web of science:	WOS:000637305900001
≡ Scopus:	2-s2.0-85107356126
≡ OpenAlex:	W3142578224