Stereoselective electrocatalytic transformation of arylidenemalononitriles and malononitrile into (1R,5S,6R)*-6-aryl-2-amino-4,4-dialkoxy-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes

Stereoselective electrocatalytic transformation of arylidenemalononitriles and malononitrile into (1R,5S,6R)*-6-aryl-2-amino-4,4-dialkoxy-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes Full article

Journal

Tetrahedron
ISSN: 0040-4020 , E-ISSN: 1464-5416

Output data

Year: 2004, Volume: 60, Number: 51, Pages: 11743-11749 Pages count : 7 DOI: 10.1016/j.tet.2004.10.003

Authors

Elinson Michail N. ¹ , Feducovich Sergey K. ¹ , Starikova Zoya A. ² , Vereshchagin Anatolii N. ¹ , Nikishin Gennady I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prospect 47, 119991 Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, ul. Vavilova 28, 119991 Moscow, Russian Federation

Electrolysis of arylidenemalononitriles and malononitrile in alcohols in an undivided cell in the presence of sodium bromide as mediator results in the stereoselective formation of (1R,2S,6R)*-6-aryl-2-amino-4,4-dialkoxy-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes in 60–80% yields.

Elinson M.N. , Feducovich S.K. , Starikova Z.A. , Vereshchagin A.N. , Nikishin G.I.
Stereoselective electrocatalytic transformation of arylidenemalononitriles and malononitrile into (1R,5S,6R)*-6-aryl-2-amino-4,4-dialkoxy-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes
Tetrahedron. 2004. V.60. N51. P.11743-11749. DOI: 10.1016/j.tet.2004.10.003 Scopus OpenAlex

Scopus:	2-s2.0-8444233543
OpenAlex:	W2949834021

DB	Citing
OpenAlex	29
Scopus	34