Tris(pentafluorophenyl)silyl enol ethers: synthesis and aldol reactions

Tris(pentafluorophenyl)silyl enol ethers: synthesis and aldol reactions Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 2004, Volume: 45, Number: 19, Pages: 3741-3744 Pages count : 4 DOI: 10.1016/j.tetlet.2004.03.090

Authors

Dilman Alexander D ¹ , Belyakov Pavel A ¹ , Korlyukov Alexander A ² , Tartakovsky Vladimir A ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, 119991 Moscow, Vavilov str. 28, Russian Federation

Silyl enol ethers bearing three pentafluorophenyl groups at the silicon atom are described. These compounds undergo uncatalyzed aldol reactions with aliphatic, α,β-unsaturated, and aromatic aldehydes. The observed reactivity is analyzed in terms of the Lewis acidity of the silyl fragment. Tris(pentafluorophenyl)silyl enol ethers have been prepared and involved in uncatalyzed aldol reactions.

Dilman A.D. , Belyakov P.A. , Korlyukov A.A. , Tartakovsky V.A.
Tris(pentafluorophenyl)silyl enol ethers: synthesis and aldol reactions
Tetrahedron Letters. 2004. V.45. N19. P.3741-3744. DOI: 10.1016/j.tetlet.2004.03.090 Scopus OpenAlex

Scopus:	2-s2.0-1842850687
OpenAlex:	W2949763018

DB	Citing
OpenAlex	12
Scopus	11