Carboxylation of styrene in the N(C4H9)4Br—heptane system

Carboxylation of styrene in the N(C4H9)4Br—heptane system Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2004, Volume: 53, Number: 11, Pages: 2564-2567 Pages count : 4 DOI: 10.1007/s11172-005-0155-1

Authors

Lapidus A.L. ¹ , Eliseev O.L. ¹ , Stepin N.N. ¹ , Bondarenko T.N. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

The carboxylation of styrene into carboxylic acids in the N(C4H9)4Br—heptane system in the presence of phosphine complexes and palladium acetate was studied. In the absence of phosphine, the Pd catalyst seems to be stabilized in solution by forming anionic complexes with NBu4Br; the stabilization depends on the acidity of the reaction medium. The catalytic system can be used repeatedly, its activity being reduced only slightly.

Lapidus A.L. , Eliseev O.L. , Stepin N.N. , Bondarenko T.N.
Carboxylation of styrene in the N(C4H9)4Br—heptane system
Russian Chemical Bulletin. 2004. V.53. N11. P.2564-2567. DOI: 10.1007/s11172-005-0155-1 WOS Scopus OpenAlex

Web of science:	WOS:000228070800022
Scopus:	2-s2.0-21644435339
OpenAlex:	W2950076117

DB	Citing
OpenAlex	7
Scopus	11
Web of science	10