Carbonylation of -Haloketones | Sciact

Carbonylation of -Haloketones Full article

Journal

Kinetics and Catalysis
ISSN: 1608-3210 , E-ISSN: 0023-1584

Output data

Year: 2004, Volume: 45, Number: 2, Pages: 234-238 Pages count : 5 DOI: 10.1023/b:kica.0000023797.89865.e5

Authors

Lapidus A.L. ¹ , Eliseev O.L. ¹ , Bondarenko T.N. ¹ , Sizan O.E. ¹ , Ostapenko E.G. ¹ , Beletskaya I.P. ²

Affiliations

1	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
2	Moscow State University, Moscow, 119899 Russia

The catalytic carbonylation reactions of α-haloketones in the presence of palladium compounds were studied. Chloroketones were selectively converted into β-ketoesters, whereas bromoacetophenone was partially reduced to acetophenone. The reaction rate at atmospheric pressure was much lower than that at an elevated pressure. A reaction mechanism was proposed.

Lapidus A.L. , Eliseev O.L. , Bondarenko T.N. , Sizan O.E. , Ostapenko E.G. , Beletskaya I.P.
Carbonylation of -Haloketones
Kinetics and Catalysis. 2004. V.45. N2. P.234-238. DOI: 10.1023/b:kica.0000023797.89865.e5 WOS Scopus OpenAlex

Web of science:	WOS:000221291000012
Scopus:	2-s2.0-3543092681
OpenAlex:	W2497063507

DB	Citing
OpenAlex	8
Web of science	8
Scopus	9