Electrochemical transformations of monooxa- and dioxabicycloalkenes and-bicycloalkanes

Electrochemical transformations of monooxa- and dioxabicycloalkenes and-bicycloalkanes Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 1999, Volume: 48, Number: 11, Pages: 2091-2099 Pages count : 9 DOI: 10.1007/bf02494854

Authors

Ogibin Yu.N. ¹ , Terent'ev A.O. ¹ , Ilovaisky A.I. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Electrolysis of 2-oxa- and 2,5-dioxabicyclo[n.4.0]alk-1(6)0enes (n=4, 10) under conditions of direct undivided anodic oxidation in methanol results in their electrochemical mono-and dimethoxylation; electrolysis of the corresponding 2-oxa-and 2,5-dioxabicycloalkanes involves electrochemical cleavage of the bridging carbon—carbon bonds followed by electrooxidative transformation into methyl ω-(2-methoxytetrahydrofuryl)-, ω-(dimethoxy-methyl)-, and ω-(1,3-dioxolan-2-yl)alkanoates.

Ogibin Y.N. , Terent'ev A.O. , Ilovaisky A.I. , Nikishin G.I.
Electrochemical transformations of monooxa- and dioxabicycloalkenes and-bicycloalkanes
Russian Chemical Bulletin. 1999. V.48. N11. P.2091-2099. DOI: 10.1007/bf02494854 Scopus OpenAlex

Scopus:	2-s2.0-0033235437
OpenAlex:	W1993080143

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