Stable Pt(IV) vinylic complexes with unusual regioselectivity formed in the reaction of methylpropiolate triple bond activation

Stable Pt(IV) vinylic complexes with unusual regioselectivity formed in the reaction of methylpropiolate triple bond activation Научная публикация

Журнал

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Вых. Данные

Год: 2001, Том: 636, Номер: 1-2, Страницы: 175-181 Страниц : 7 DOI: 10.1016/s0022-328x(01)01052-x

Авторы

Ananikov Valentine P ¹ , Mitchenko Sergey A ² , Beletskaya Irina P ³

Организации

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky Prospect 47, Moscow, 117913, Russia
2	A.N. Nesmeyanov Institute of Organoelemental Compounds, Moscow, 117813, Russia
3	M.V. Lomonosov Moscow State University, Moscow, 119899, Russia

An unusual fact of HCCCOOMe triple bond activation by Pt(IV) iodide leading to the formation of new bis-σ-vinyl complexes [Pt(CHCICOOMe)(CIHCCOOMe)(Sol)3−nIn]2−n (where n=2, 3) with different regioselectivity in vinyl ligands is reported. The isolated complex can be involved in C–C coupling reaction resulting in a head-to-tail connection of vinyl groups in a substituted diene unit. Regioselectivity switching upon triple bond activation results in a head-to-tail connection of vinyl groups in a substituted diene unit after the C–C coupling reaction.

Ananikov V.P. , Mitchenko S.A. , Beletskaya I.P.
Stable Pt(IV) vinylic complexes with unusual regioselectivity formed in the reaction of methylpropiolate triple bond activation
Journal of Organometallic Chemistry. 2001. V.636. N1-2. P.175-181. DOI: 10.1016/s0022-328x(01)01052-x Scopus OpenAlex

Scopus:	2-s2.0-0012838824
OpenAlex:	W2027480551

БД	Цитирований
OpenAlex	16
Scopus	20