Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates

Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 1999, Volume: 9, Number: 5, Pages: 194-195 Pages count : 2 DOI: 10.1070/mc1999v009n05abeh001133

Authors

Ogibin Yuri N. ¹ , Terent’ev Alexander O. ¹ , Ilovaisky Alexey I. ¹ , Nikishin Gennady I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russsian Academy of Sciences, 117913 Moscow, Russian Federation

Anodic oxidation of 2,5-dioxabicyclo[4.4.0]decane 1a, 1-methoxy-2,5-dioxabicyclo[4.4.0]decane 1b and 1-hydroxy-2,5-dioxabicyclo[ 4.4.0]decane 1c in methanol in the presence of tetrabutylammonium fluoroborate as a supporting electrolyte induces the electrooxidative transformation of substrates 1a and 1b into methyl 5-(dimethoxymethyl)pentanoate and of substrate 1c into methyl 5-(1,3-dioxolan-2-yl)pentanoate.

Ogibin Y.N. , Terent’ev A.O. , Ilovaisky A.I. , Nikishin G.I.
Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates
Mendeleev Communications. 1999. V.9. N5. P.194-195. DOI: 10.1070/mc1999v009n05abeh001133 OpenAlex

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