Novel energetic furazans containing isomeric N-(azoxy)-dinitropyrazole moieties: Synthesis, characterization and comparison of properties

Novel energetic furazans containing isomeric N-(azoxy)-dinitropyrazole moieties: Synthesis, characterization and comparison of properties Full article

Journal

Energetic Materials Frontiers
ISSN: 2666-6472

Output data

Year: 2023, Volume: 4, Number: 1, Pages: 1-9 Pages count : 9 DOI: 10.1016/j.enmf.2022.10.001

Authors

A. A. Konnov Alexey A. ¹ , M. S. Klenov Michael S. ¹ , A. M. Churakov Aleksandr M. ¹ , Dalinger Igor L. ¹ , Strelenko Yurii A. ¹ , Fedyanin Ivan V. ^2,3 , David B. Lempert ⁴ , Alla N. Pivkina ⁵ , Tatiana S. Kon'kova ⁵ , Matyushin Yurii N. ⁵ , Tartakovsky Vladimir A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, 119991, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds Russian Academy of Sciences, Moscow, 119991, Russian Federation
3	Plekhanov Russian University of Economics, Moscow, 117997, Russian Federation
4	Institute of Problems of Chemical Physics Russian Academy of Sciences, Chernogolovka, 142432, Moscow Region, Russian Federation
5	N. N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences, Moscow, 119991, Russian Federation

Novel energetic furazans 3a–3c and 4a–4c containing isomeric (3,4-dinitro-1H-pyrazol-1-yl)-NNO-azoxy and (3,5-dinitro-1H-pyrazol-1-yl)-NNO-azoxy moieties have been obtained. A synthetic approach to aminofurazans 3a and 4a involves the reaction of 1-amino-3,4-dinitro-1H-pyrazole or 1-amino-3,5-dinitro-1H-pyrazole with 2,2,2-trifluoro-N-(4-nitrosofurazan-3-yl)acetamide and dibromoisocyanuric acid, followed by removal of the trifluoroacetyl group. Transformations of the amino group in aminofurazans 3a and 4a gave the corresponding nitro (3b, 4b) and azo (3c,4c) substituted furazans. The compounds synthesized exhibit high experimental enthalpies of formation (2093–2847 kJ⋅kg1), good thermal stabilities (onset decomposition temperatures 203–228 C), acceptable densities(1.78–1.87 g⋅cm3) and high detonation parameters (detonation velocities D ¼ 8.71–8.99 km s1, detonation pres-sures p ¼ 33.9–38.7 GPa). Nitro substituted furazans 3b, 4b and azo substituted furazans 3c, 4c have been evaluated as effective energetic fillers for solid composite propellants, providing specific impulse values 9–11 s higher than similar formulations based on RDX and HMX, and 4–6 s higher than similar formulations based on CL-20

A. A. Konnov A.A. , M. S. Klenov M.S. , A. M. Churakov A.M. , Dalinger I.L. , Strelenko Y.A. , Fedyanin I.V. , David B. L. , Alla N. P. , Tatiana S. K. , Matyushin Y.N. , Tartakovsky V.A.
Novel energetic furazans containing isomeric N-(azoxy)-dinitropyrazole moieties: Synthesis, characterization and comparison of properties
Energetic Materials Frontiers. 2023. V.4. N1. P.1-9. DOI: 10.1016/j.enmf.2022.10.001 Scopus OpenAlex

≡ Scopus:	2-s2.0-85144944696
≡ OpenAlex:	W4306777649