Preparation of Propanols by Glycerol Hydrogenolysis over Bifunctional Nickel-Containing Catalysts

Preparation of Propanols by Glycerol Hydrogenolysis over Bifunctional Nickel-Containing Catalysts Full article

Journal

Molecules
ISSN: 1420-3049

Output data

Year: 2021, Volume: 26, Number: 6, Article number : 1565, Pages count : DOI: 10.3390/molecules26061565

Authors

Greish Alexander A. ¹ , Finashina Elena D. ¹ , Tkachenko Olga P. ¹ , Kustov Leonid M. ^1,2,3

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky Prospect, 47, 119991 Moscow, Russia.
2	Chemistry Department, Lomonosov Moscow State University, Leninskie Gory, 1, bldg. 3, 119991 Moscow, Russia
3	Laboratory of Nanochemistry and Ecology, Institute of Environmental Technologies & Engineering, National University of Science and Technology “MISiS”, Leninsky Prospect, 4, 119049 Moscow, Russia

The paper presents the results obtained in studying glycerol hydrogenolysis into 1-propanol and 2-propanol over bifunctional Ni/WO3-TiO2 and Ni/WO3-ZrO2 catalysts in the flow system. Due to the optimal combination of acidic and hydrogenation properties of the heterogeneous catalysts, they exhibit higher performance in glycerol conversion into C3 alcohols, although the process is carried out in rather mild conditions. At the reaction temperature of 250 °C and hydrogen pressure of 3 MPa, the total yield of 1-propanol and 2-propanol reaches 95%, and the glycerol conversion is close to 100%.

Greish A.A. , Finashina E.D. , Tkachenko O.P. , Kustov L.M.
Preparation of Propanols by Glycerol Hydrogenolysis over Bifunctional Nickel-Containing Catalysts
Molecules. 2021. V.26. N6. 1565 . DOI: 10.3390/molecules26061565 WOS Scopus OpenAlex

Web of science:	WOS:000645400100001
Scopus:	2-s2.0-85103862832
OpenAlex:	W3137810299

DB	Citing
OpenAlex	14
Scopus	12
Web of science	11