Revealing the Mechanism of Combining Best Properties of Homogeneous and Heterogeneous Catalysis in Hybrid Pd/NHC Systems

Revealing the Mechanism of Combining Best Properties of Homogeneous and Heterogeneous Catalysis in Hybrid Pd/NHC Systems Full article

Journal

Angewandte Chemie International Edition
ISSN: 1433-7851 , E-ISSN: 1521-3773

Output data

Year: 2024, Volume: 63, Number: 27, DOI: 10.1002/anie.202317468

Authors

Prima Darya O. ¹ , Kulikovskaya Natalia S. ¹ , Novikov Roman A. ¹ , Kostyukovich Alexander Yu. ¹ , Burykina Julia V. ¹ , Chernyshev Victor M. ² , Ananikov Valentine P. ¹

Affiliations

1	FSBIS N D Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, Chemistry, RUSSIAN FEDERATION
2	Platov South-Russian State Polytechnic University (NPI) Prosveschenya 132 Novocherkassk 346428 Russia.

This research explores the formation of hybrid nanoscale metal species from molecular precatalysts, which exhibit the unique attributes of molecular complexes and nanoparticles. This study addresses their detection difficulties and introduces solid-state NMR to demonstrate the generation of catalytically active Pd nanoparticles from Pd/NHC complexes. The findings underscore the critical role of NHC ligands in catalytic nanoparticle system stability and activity.

Prima D.O. , Kulikovskaya N.S. , Novikov R.A. , Kostyukovich A.Y. , Burykina J.V. , Chernyshev V.M. , Ananikov V.P.
Revealing the Mechanism of Combining Best Properties of Homogeneous and Heterogeneous Catalysis in Hybrid Pd/NHC Systems
Angewandte Chemie International Edition. 2024. V.63. N27. DOI: 10.1002/anie.202317468 Scopus OpenAlex

Scopus:	2-s2.0-85194968483
OpenAlex:	W4393949066

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