Electrochemically induced Favorsky rearrangement: transformations of dialkyl ketones into α,β-unsaturated carboxylic esters

Electrochemically induced Favorsky rearrangement: transformations of dialkyl ketones into α,β-unsaturated carboxylic esters Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2003, Volume: 52, Number: 4, Pages: 998-1002 Pages count : 5 DOI: 10.1023/a:1024481216415

Authors

Elinson M.N. ¹ , Feducovich S.K. ¹ , Zaimovskaya T.A. ² , Dorofeev A.S. ¹ , Vereshchagin A.N. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Electrolysis of dialkyl ketones in MeOH in the presence of the NaI—NaOH mediator system placed in an undivided cell involves a process analogous to the Favorsky rearrangement of α,α-dihalodialkyl ketones giving rise to methyl esters of α,β-unsaturated carboxylic acids in 70—75% substance yields and 60—70% current yields.

Elinson M.N. , Feducovich S.K. , Zaimovskaya T.A. , Dorofeev A.S. , Vereshchagin A.N. , Nikishin G.I.
Electrochemically induced Favorsky rearrangement: transformations of dialkyl ketones into α,β-unsaturated carboxylic esters
Russian Chemical Bulletin. 2003. V.52. N4. P.998-1002. DOI: 10.1023/a:1024481216415 Scopus OpenAlex

Scopus:	2-s2.0-0037745013
OpenAlex:	W2950882919

DB	Citing
OpenAlex	7
Scopus	4