Stereoselective electrochemical transformation of alkylidenecyanoacetates and malonate into (E)-3-substituted-2-cyanocyclopropane-1,1,2-tricarboxylates

Stereoselective electrochemical transformation of alkylidenecyanoacetates and malonate into (E)-3-substituted-2-cyanocyclopropane-1,1,2-tricarboxylates Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 2000, Volume: 41, Number: 25, Pages: 4937-4941 Pages count : 5 DOI: 10.1016/s0040-4039(00)00733-4

Authors

Elinson Michail N ¹ , Feducovich Sergey K ¹ , Starikova Zoya A ² , Olessova Olga S ¹ , Vereshchagin Anatolii N ¹ , Nikishin Gennady I ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 117913 Moscow B-334, Russia
2	A.N. Nesmeyanov Institute of Organoelement Compounds, ul. Vavilova 28, 117813 Moscow B-334, Russia

Electrolysis of malonate and alkylidenecyanoacetates in alcohols in the presence of sodium bromide in an undivided cell results in the stereoselective formation of (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates in 75–85% yields.

Elinson M.N. , Feducovich S.K. , Starikova Z.A. , Olessova O.S. , Vereshchagin A.N. , Nikishin G.I.
Stereoselective electrochemical transformation of alkylidenecyanoacetates and malonate into (E)-3-substituted-2-cyanocyclopropane-1,1,2-tricarboxylates
Tetrahedron Letters. 2000. V.41. N25. P.4937-4941. DOI: 10.1016/s0040-4039(00)00733-4 Scopus OpenAlex

Scopus:	2-s2.0-0034686211
OpenAlex:	W2952535205

DB	Citing
OpenAlex	39
Scopus	39