Electrochemical cleavage of a benzylic C-C bond in arylaliphatic compounds Научная публикация
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Вых. Данные | Год: 1993, Том: 42, Номер: 1, Страницы: 126-128 Страниц : 3 DOI: 10.1007/bf00699992 | ||
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Реферат:
Electrochemical cleavage of a benzylic C-C bond in arylaliphatic compounds and the effect of the structure of their alkyl and aryl fragments on the process are studied. Cleavage was found to be the most effective for substituted benzenes and anisoles with side chains bearing vicinal methoxy- and hydroxy-groups in the a- and β-positions. Cleavage was moderate for cior β-methoxy(hydroxy)- and (β,β-dialkoxyalkyl)arenes. Electrolysis carried out in methanol results in formation of PhCH2OMe and PhCH(OMe)2 from PhCH2R and PhCH(OMe)R, benzaldehyde from (1,2-dihydroxypropyl)benzene, acetophenone from 2-phenylhexan-2-ol, 4-MeOC6H4CH(OMe)2 from 4-(1,2-dimethoxypropyl)anisole, and 2-(MeO)2CHC6H4CH(OMe)2 from 1,2-dimethoxyindan.
Библиографическая ссылка:
Ogibin Y.N.
, Ilovaiskii A.I.
, Nikishin G.I.
Electrochemical cleavage of a benzylic C-C bond in arylaliphatic compounds
Russian Chemical Bulletin. 1993. V.42. N1. P.126-128. DOI: 10.1007/bf00699992 WOS Scopus OpenAlex
Electrochemical cleavage of a benzylic C-C bond in arylaliphatic compounds
Russian Chemical Bulletin. 1993. V.42. N1. P.126-128. DOI: 10.1007/bf00699992 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:A1993MM95700030 |
| Scopus: | 2-s2.0-5244245322 |
| OpenAlex: | W2011738848 |