Tetramethylsilane as reagent gas: mass spectra of nitrocarboxylic acid esters and nitroalcohols

Tetramethylsilane as reagent gas: mass spectra of nitrocarboxylic acid esters and nitroalcohols Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 1998, Volume: 47, Number: 6, Pages: 1225-1228 Pages count : 4 DOI: 10.1007/bf02503504

Authors

Kadentsev V.I. ¹ , Kolotyrkina N.G. ¹ , Stomakhin A.A. ¹ , Chizhov O S. ¹ , Ioffe S.L. ¹ , Lypkalo I.M. ¹ , Dil'man A.D. ¹ , Tishkov A.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

Nitrocarboxylic acid esters and nitroalcohols react with trimethylsilyl cation in the gas phase under conditions of chemical ionization to form stable [M+SiMe3]+ ions. The pathways of their fragmentation were established and characteristic distinctions in the mass spectra caused by mutual arrangement of functional groups were found.

Kadentsev V.I. , Kolotyrkina N.G. , Stomakhin A.A. , Chizhov O.S. , Ioffe S.L. , Lypkalo I.M. , Dil'man A.D. , Tishkov A.A.
Tetramethylsilane as reagent gas: mass spectra of nitrocarboxylic acid esters and nitroalcohols
Russian Chemical Bulletin. 1998. V.47. N6. P.1225-1228. DOI: 10.1007/bf02503504 Scopus OpenAlex

Scopus:	2-s2.0-0042858333
OpenAlex:	W2087756712

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