Electrochemical cleavage of bridged C-C bonds in bicyclic enol ethers and monooxa- and dioxabicycloalkanes: An approach to macrocyclic compounds

Electrochemical cleavage of bridged C-C bonds in bicyclic enol ethers and monooxa- and dioxabicycloalkanes: An approach to macrocyclic compounds Full article

Journal

Russian Journal of Electrochemistry
ISSN: 1023-1935 , E-ISSN: 1608-3342

Output data

Year: 2000, Volume: 36, Number: 2, Pages: 193-202 Pages count : 10 DOI: 10.1007/bf02756906

Authors

Ogibin Yu.N. ¹ , Terent’ev A.O. ¹ , Ilovaiskii A.I. ¹ , Nikishin G.I. ¹

Affiliations

1	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 117913, Moscow, Russia

Electrolysis of bicyclic enol ethers in methanol results in their electrochemical mono-and dimethoxylation. Electrolysis of monooxa-and dioxabicycloalkanes leads to the electrochemical cleavage of their bridged C-C bonds and electrooxidative conversion into esters of Ω-(2-methoxytetrahydrofuryl)-, Ω-(dimethoxymethyl)-, and Ω-(l,3-dioxalan-2-yl) alkanoic acids.

Ogibin Y.N. , Terent’ev A.O. , Ilovaiskii A.I. , Nikishin G.I.
Electrochemical cleavage of bridged C-C bonds in bicyclic enol ethers and monooxa- and dioxabicycloalkanes: An approach to macrocyclic compounds
Russian Journal of Electrochemistry. 2000. V.36. N2. P.193-202. DOI: 10.1007/bf02756906 Scopus OpenAlex

Scopus:	2-s2.0-0033807247
OpenAlex:	W2005711362

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