Electrochemical hydrocarboxylation of enol derivatives with CO2: access to β‑acetoxycarboxylic acids

Electrochemical hydrocarboxylation of enol derivatives with CO2: access to β‑acetoxycarboxylic acids Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2024, Volume: 60, Pages: 8099-8102 Pages count : 4 DOI: 10.1039/d4cc02831g

Authors

Ustyuzhanin Alexander O ¹ , Bityukov Oleg V ¹ , Sokolovskiy Pavel V ¹ , Merkulova Valentina M ¹ , Ilovaisky Alexey I ¹ , He Liang-Nian ² , Vil' Vera A ¹ , Terent'ev Alexander O ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russian Federation. vil@ioc.ac.ru.
2	State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.

Electrochemical hydrocarboxylation of enol acetates with CO2 is developed. The disclosed process provides β-acetoxycarboxylic acids in 25–66% yields, in contrast to the electrolysis of ketones, silyl enol ethers and vinyl tosylates with CO2, which leads mainly to alcohols.

Ustyuzhanin A.O. , Bityukov O.V. , Sokolovskiy P.V. , Merkulova V.M. , Ilovaisky A.I. , He L-N. , Vil' V.A. , Terent'ev A.O.
Electrochemical hydrocarboxylation of enol derivatives with CO2: access to β‑acetoxycarboxylic acids
Chemical Communications. 2024. V.60. P.8099-8102. DOI: 10.1039/d4cc02831g Scopus OpenAlex

Scopus:	2-s2.0-85198996257
OpenAlex:	W4400414204

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