Synthesis and structure of [Pt(CH=CI-CH2OCH3)2(I)2] as possible intermediate of catalytic alkynes conversion reaction into diiodosubstituted dienes

Synthesis and structure of [Pt(CH=CI-CH2OCH3)2(I)2] as possible intermediate of catalytic alkynes conversion reaction into diiodosubstituted dienes Full article

Journal

Inorganic Chemistry Communications
ISSN: 1387-7003 , E-ISSN: 1879-0259

Output data

Year: 1998, Volume: 1, Number: 11, Pages: 411-414 Pages count : 4 DOI: 10.1016/s1387-7003(98)00102-6

Authors

Ananikov Valentin ¹ , Mitchenko Sergey A. ² , Beletskaya Irina P. ³ , Nefedov Sergey E. ⁴ , Eremenko Igor L. ⁴

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky Prospect 47, Moscow 117913, Russia
2	A.N. Nesmeyanov Institute of Organoelemental Compounds, Moscow 117813, Russia
3	M.V. Lomonosov Moscow State University, Moscow 119899, Russia
4	N.S. Kurnakov Institute of General and Inorganic Chemistry, GSP-1, 31 Leninsky Prospect, Moscow 117907, Russia

Direct evidence was found that catalytic alkynes conversion reaction in the system Pt(IV)-I−-I2 proceeds through a platinum(IV) σ-vinyl complex. A synthesis, X-ray structure determination, and a multinuclear NMR study of the key-intermediate complex [Pt(CH=CI-CH2OCH3)2(I)2] as well as an expansion of the catalytic reaction are shown.

Ananikov V. , Mitchenko S.A. , Beletskaya I.P. , Nefedov S.E. , Eremenko I.L.
Synthesis and structure of [Pt(CH=CI-CH2OCH3)2(I)2] as possible intermediate of catalytic alkynes conversion reaction into diiodosubstituted dienes
Inorganic Chemistry Communications. 1998. V.1. N11. P.411-414. DOI: 10.1016/s1387-7003(98)00102-6 Scopus OpenAlex

Scopus:	2-s2.0-0001540423
OpenAlex:	W2088732169

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