Synthesis and Calculation of Properties of N-Difluoroaminoazoles, the Novel Type of Energetic Materials Научная публикация
| Журнал |
Propellants, Explosives, Pyrotechnics
ISSN: 0721-3115 , E-ISSN: 1521-4087 |
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| Вых. Данные | Год: 1998, Том: 23, Номер: 4, Страницы: 212-217 Страниц : 6 DOI: 10.1002/(sici)1521-4087(199808)23:4<212::aid-prep212>3.0.co;2-y | ||
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| Организации |
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Реферат:
A novel class of energetic materials, N-difluoroaminonitroazoles was synthesized. One molecule of these compounds contains simultaneously a nitro group and difluoroamine one. A method of synthesizing N-difluoroaminonitroazoles incorporates the interaction of N-unsubstituted nitroazoles with O-fluorosulfonyl-N,N-difluorohydroxylamine (F2NOSO2F) in the presence of bases. To estimate possible prospects of these compounds, energy content, molecular crystal density, some parameters of detonation and combustion were calculated using some well-known methods of computational chemistry, as well as some of our original schemes. In addition, thermostability (by the DTA method) and density were identified experimentally for a cross-section row of the studied compounds. The reasons for relatively low stability of this type of substances were given.
Библиографическая ссылка:
Dalinger I.L.
, Vinogradov V.M.
, Shevelev S.A.
, Kuz’min V.S.
, Arnautova E.A.
, Pivina T.S.
Synthesis and Calculation of Properties of N-Difluoroaminoazoles, the Novel Type of Energetic Materials
Propellants, Explosives, Pyrotechnics. 1998. V.23. N4. P.212-217. DOI: 10.1002/(sici)1521-4087(199808)23:4<212::aid-prep212>3.0.co;2-y WOS Scopus OpenAlex
Synthesis and Calculation of Properties of N-Difluoroaminoazoles, the Novel Type of Energetic Materials
Propellants, Explosives, Pyrotechnics. 1998. V.23. N4. P.212-217. DOI: 10.1002/(sici)1521-4087(199808)23:4<212::aid-prep212>3.0.co;2-y WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000075814300009 |
| Scopus: | 2-s2.0-0032131222 |
| OpenAlex: | W2051366184 |