Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes

Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2024, Volume: 34, Number: 2, Pages: 204-205 Pages count : 2 DOI: 10.1016/j.mencom.2024.02.014

Authors

Kuznetsova Svetlana A. ¹ , Yunusov Safar M. ¹ , Khakina Ekaterina A. ¹ , Naumkin Alexander V. ¹ , Chusov Denis A. ¹ , Kalyuzhnaya Elena S. ¹ , Ilyin Mikhail M. ¹ , Morozov Viacheslav V. ^1,2 , Kashin Alexey S. ³ , Belokon Yuri N. ¹

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334 Moscow, Russian Federation
2	D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
3	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A novel catalyst based on Pd nanoparticles encapsulated in a chiral crystalline organic salt matrix is prepared from tetrasodium tetrakis(4-sulfonatophenyl)methane and tetrakis[4-(S)-prolinamidophenyl]methane in water at room temperature under hydrogen atmosphere. The hydrogenation of p-nitrobenzaldehyde over this catalyst stalls at the stage of p-aminobenzyl alcohol, whereas Pd/C brings the reduction further to p-toluidine.

Kuznetsova S.A. , Yunusov S.M. , Khakina E.A. , Naumkin A.V. , Chusov D.A. , Kalyuzhnaya E.S. , Ilyin M.M. , Morozov V.V. , Kashin A.S. , Belokon Y.N.
Chiral crystalline organic salts as supports of Pd nanoparticles forming selective heterogeneous catalysts for hydrogenation of nitroarenes
Mendeleev Communications. 2024. V.34. N2. P.204-205. DOI: 10.1016/j.mencom.2024.02.014 WOS Scopus OpenAlex

≡ Web of science:	WOS:001221396900001
≡ Scopus:	2-s2.0-85189542382
≡ OpenAlex:	W4393857072