Electrochemical behavior of a flat gold electrode in an acetonitrile solution of 1,2,4,5-tetraoxane

Electrochemical behavior of a flat gold electrode in an acetonitrile solution of 1,2,4,5-tetraoxane Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2024, Volume: 73, Number: 4, Pages: 863-870 Pages count : 8 DOI: 10.1007/s11172-024-4200-3

Authors

Polyakov M.V. ¹ , Vedenyapina M.D. ¹ , Skundin A.M. ² , Yaremenko I.A. ¹ , Radulov P.S. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Build. 4, 31 Leninsky prosp., 119071, Moscow, Russian Federation

The electrochemical behavior of a flat gold electrode in an acetonitrile solution of 3-(1,4-dimethyl-2,3,5,6-tetraoxabicyclo[2.2.1]hept-7-yl)propanoic acid was studied by cyclic voltammetry. The formation of colloidal gold particles was detected during the anodic oxidation. The kinetics of their formation was studied by the gravimetric method. Peroxide bonds in the cyclic peroxide molecule were found to be reduced on the cathode surface with the subsequent formation of the diketone fragment.

Polyakov M.V. , Vedenyapina M.D. , Skundin A.M. , Yaremenko I.A. , Radulov P.S.
Electrochemical behavior of a flat gold electrode in an acetonitrile solution of 1,2,4,5-tetraoxane
Russian Chemical Bulletin. 2024. V.73. N4. P.863-870. DOI: 10.1007/s11172-024-4200-3 WOS Scopus OpenAlex

Web of science:	WOS:001235375600011
Scopus:	2-s2.0-85192205615
OpenAlex:	W4396709972

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OpenAlex	3
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