Synthesis of functionalized 2-diphenylphosphinoethyl-containing phosphonous and phosphinic acids

Synthesis of functionalized 2-diphenylphosphinoethyl-containing phosphonous and phosphinic acids Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2024, Том: 73, Номер: 2, Страницы: 379-386 Страниц : 8 DOI: 10.1007/s11172-024-4145-6

Авторы

Prishchenko A.A. ¹ , Livantsov M.V. ¹ , Novikova O.P. ¹ , Livantsova L.I. ¹ , Baranin S.V. ² , Bubnov Yu.N. ^2,3

Организации

1	Chemical Department, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991 Moscow, Russian Federation

A convenient synthesis of functionalized 2-diphenylphosphinoethyl-containing phosphonous and phosphinic acids has been developed. Radical addition of bis(trimethylsiloxy)-phosphine to diphenyl(vinyl)phosphine and phenyl(divinyl)phosphine proceeds regioselectively to give new 2-phosphino-substituted ethylphosphonites, the subsequent functionalization of which affords the target phosphinic acids and a variety of their derivatives. The resulting compounds are of interest as effective water-soluble ligands and promising biologically active substances.

Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V. , Bubnov Y.N.
Synthesis of functionalized 2-diphenylphosphinoethyl-containing phosphonous and phosphinic acids
Russian Chemical Bulletin. 2024. V.73. N2. P.379-386. DOI: 10.1007/s11172-024-4145-6 WOS Scopus OpenAlex

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