Sciact
  • EN
  • RU

Highly selective Pd-catalyzed hydroxycarbonylation of styrene Full article

Journal Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Output data Year: 2024, Volume: 73, Number: 5, Pages: 1197-1200 Pages count : 4 DOI: 10.1007/s11172-024-4235-5
Authors Eliseev O.L. 1 , Bondarenko T.N. 1 , Tsapkina M.V. 1 , Lapidus A.L. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

Abstract: The hydrocarboxylation of styrene in the presence of PdCl2(PPh3)2 was studied to investigate the influence of the nature of the solvent, promoters, and reaction conditions on the yield of the target 2-phenylpropionic acid. Cation exchange resins Amberlyst 15 and KU-2 were proposed as suitable alternatives to liquid acid promoters, making it possible to achieve a high catalytic activity with up to 99% regioselectivity.
Cite: Eliseev O.L. , Bondarenko T.N. , Tsapkina M.V. , Lapidus A.L.
Highly selective Pd-catalyzed hydroxycarbonylation of styrene
Russian Chemical Bulletin. 2024. V.73. N5. P.1197-1200. DOI: 10.1007/s11172-024-4235-5 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:001252371600002
Scopus: 2-s2.0-85196512983
OpenAlex: W4399899629
Citing:
DB Citing
OpenAlex 1
Scopus 1
Web of science 1
Altmetrics: