Manganese triacetate as an efficient catalyst for bisperoxidation of styrenes

Manganese triacetate as an efficient catalyst for bisperoxidation of styrenes Full article

Journal

Organic & Biomolecular Chemistry
ISSN: 1477-0520 , E-ISSN: 1477-0539

Output data

Year: 2015, Volume: 13, Number: 5, Pages: 1439-1445 Pages count : 7 DOI: 10.1039/c4ob01823k

Authors

Terent'ev Alexander O. ^1,2 , Sharipov Mikhail Yu. ^1,2 , Krylov Igor B. ¹ , Gaidarenko Darya V. ² , Nikishin Gennady I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow, Russian Federation
2	D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square,Moscow,Russian Federation

A method was developed for the bisperoxidation of styrenes with tert-butyl hydroperoxide in the presence of a catalytic amount of manganese(III) acetate. It was shown that compounds of manganese in oxidation states 2, 4, and 7 also catalyze this reaction. The target [1,2-bis(tert-butylperoxy)ethyl]arenes were synthesized in yields from 46 to 75%.

Terent'ev A.O. , Sharipov M.Y. , Krylov I.B. , Gaidarenko D.V. , Nikishin G.I.
Manganese triacetate as an efficient catalyst for bisperoxidation of styrenes
Organic & Biomolecular Chemistry. 2015. V.13. N5. P.1439-1445. DOI: 10.1039/c4ob01823k WOS Scopus OpenAlex

≡ Web of science:	WOS:000348212300020
≡ Scopus:	2-s2.0-84921449574
≡ OpenAlex:	W2023264490