Synthesis of functionalized phosphorus-containing tetraorganosilanes

Synthesis of functionalized phosphorus-containing tetraorganosilanes Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2023, Volume: 72, Number: 3, Pages: 715-723 Pages count : 9 DOI: 10.1007/s11172-023-3836-9

Authors

Prishchenko A.A. ¹ , Livantsov M.V. ¹ , Novikova O.P. ¹ , Livantsova L.I. ¹ , Baranin S.V. ² , Bubnov Yu.N. ²

Affiliations

1	M. V. Lomonosov Moscow State Universitry, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninskii prosp., 119991, Moscow, Russian Federation

A convenient synthesis of functionalized β-phosphorus-substituted tetraorganosilanes containing hydrolysis-resistant organosilicon moieties comprises radical addition of bis(trimethylsiloxy)phosphine to substituted vinyl- and divinylsilanes. The reaction proceeds regioselectively to form new silicon-containing ethyl phosphonites, the subsequent functionalization of which affords target different-structure tetraorganosilanes.

Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V. , Bubnov Y.N.
Synthesis of functionalized phosphorus-containing tetraorganosilanes
Russian Chemical Bulletin. 2023. V.72. N3. P.715-723. DOI: 10.1007/s11172-023-3836-9 WOS Scopus OpenAlex

≡ Web of science:	WOS:001031662300014
≡ Scopus:	2-s2.0-85153204162
≡ OpenAlex:	W4365814418