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The First Synthesis of Norbornadiene Tetramers Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 1992, Volume: 2, Number: 2, Pages: 56-57 Pages count : 2 DOI: 10.1070/mc1992v002n02abeh000130
Authors Dzhemilev Usein M. 1 , Khusnutdinov Ravil’ I. 1 , Galeev Damir Kh. 1 , Malikov Alexsander I. 1 , Nefedov Oleg M. 2 , Tomilov Yuri V. 2
Affiliations
1 Institute of Organic Chemistry, Ural Branch of the Russian Academy of Sciences, 450054 Ufa, Russian Federation
2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow, Russian Federation

Abstract: Norbornadiene tetramers exo-trans-exo-trans-exo-endo-dodecacyclo[14.9.1.14,13.17,10.02,15.03,14.05,12.06,11.017,25.018,23.019,21.020,24]octacos-8-ene 2 and exo-trans-exo-trans-exo-exo-dodecacyclo[14.9.1.14,13.17,10.02,15.03,14.05,12.06,11.017,25.018,23.019,21.020.24]octanos-8-ene 3 have been synthesized in 32% total yield, via Pd complex catalysed cyclodimerization of a known norbornadiene trimer exo-trans-exo-trans-exo-octacyclo[8.8.1.14,7.113,16.02,9.03,8.011,18.012,17]henicosa-5,14-diene 1 with quadricyclane.
Cite: Dzhemilev U.M. , Khusnutdinov R.I. , Galeev D.K. , Malikov A.I. , Nefedov O.M. , Tomilov Y.V.
The First Synthesis of Norbornadiene Tetramers
Mendeleev Communications. 1992. V.2. N2. P.56-57. DOI: 10.1070/mc1992v002n02abeh000130 Scopus OpenAlex
Identifiers:
≡ Scopus: 2-s2.0-84935372495
≡ OpenAlex: W2951336968
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