Cyclopropanation of Unsaturated Compounds with Diazomethane Generated in situ: A New Efficient and Practical Route to Cyclopropane Derivatives

Cyclopropanation of Unsaturated Compounds with Diazomethane Generated in situ: A New Efficient and Practical Route to Cyclopropane Derivatives Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 1992, Volume: 2, Number: 1, Pages: 13-15 Pages count : 3 DOI: 10.1070/mc1992v002n01abeh000099

Authors

Nefedov Oleg M. ¹ , Tomilov Yurii V. ¹ , Kostitsyn Andrei B. ¹ , Dzhemilev Usein M. ² , Dokitchev Vladimir A. ²

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913, Moscow (Russia)
2	Institute of Organic Chemistry, Ural Branch of the Russian Academy of Sciences, 450054 Ufa, Russia

The synthesis of the title compounds is easily achieved by the Pd-catalysed cyclopropanation of unsaturated compounds with diazomethane generated in situ from N-methyl-N-nitrosourea–KOH in CH2Cl2–Et2O.

Nefedov O.M. , Tomilov Y.V. , Kostitsyn A.B. , Dzhemilev U.M. , Dokitchev V.A.
Cyclopropanation of Unsaturated Compounds with Diazomethane Generated in situ: A New Efficient and Practical Route to Cyclopropane Derivatives
Mendeleev Communications. 1992. V.2. N1. P.13-15. DOI: 10.1070/mc1992v002n01abeh000099 Scopus OpenAlex

≡ Scopus:	2-s2.0-85007475944
≡ OpenAlex:	W2033493953