Simple synthesis of erythro-2,3,6-trimethylhepta-4,6-dien-1-ol acetate, a lasiol precursor

Simple synthesis of erythro-2,3,6-trimethylhepta-4,6-dien-1-ol acetate, a lasiol precursor Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2024, Том: 73, Номер: 5, Страницы: 1465-1468 Страниц : 4 DOI: 10.1007/s11172-024-4267-x

Авторы

Vasil’ev A.A. ¹ , Zhdankina G.M. ¹ , Zlotin S.G. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

The Wittig reaction of (methallylidene)triphenylphosphorane with erythro-4-acetoxy-2,3-dimethylbutanal afforded erythro-2,3,6-trimethylhepta-4,6-dien-1-yl acetate as a mixture of E and Z isomers in a 85: 15 ratio. 1,4-cis-Hydrogenation of the conjugated diene system in the obtained isomeric mixture provided individual acetate of lasiol (erythro-2,3,6-trimethylhept-5-en-1-ol).

Vasil’ev A.A. , Zhdankina G.M. , Zlotin S.G.
Simple synthesis of erythro-2,3,6-trimethylhepta-4,6-dien-1-ol acetate, a lasiol precursor
Russian Chemical Bulletin. 2024. V.73. N5. P.1465-1468. DOI: 10.1007/s11172-024-4267-x WOS Scopus OpenAlex

Web of science:	WOS:001252371600032
Scopus:	2-s2.0-85196427960
OpenAlex:	W4399899293

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