Synthesis of hexaarabinofuranoside bearing the 4-(3-azidopropoxy)phenyl aglycone related to the terminal fragment of polysaccharides of mycobacteria Научная публикация
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Вых. Данные | Год: 2024, Том: 73, Номер: 5, Страницы: 1417-1425 Страниц : 9 DOI: 10.1007/s11172-024-4260-4 | ||
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Реферат:
A convergent synthesis α-(1→3)-, α-(1→5), β-(1→2)-linked hexaarabinofuranoside related to the terminal fragment of lipoarabinomannan (LAM) and arabinogalactan of mycobacteria as a glycoside with 4-(3-azidopropoxy)phenyl aglycone was accomplished. 4-(3-Azidopropoxy)phenyl aglycone belongs to the class of Janus aglycones, which can be used as both a temporary protective group for the anomeric position of the carbohydrate and a (pre)spacer for the synthesis of neoglycoconjugates. The key step of the synthesis is the formation of 1,2-trans glycosidic linkage with the use of Ara-β-(1→2)-Ara p-tolylthioarabinofuranoside bearing five triisopropylsilyl groups.
Библиографическая ссылка:
Abronina P.I.
, Malysheva N.N.
, Zinin A.I.
, Kolotyrkina N.G.
, Kononov L.O.
Synthesis of hexaarabinofuranoside bearing the 4-(3-azidopropoxy)phenyl aglycone related to the terminal fragment of polysaccharides of mycobacteria
Russian Chemical Bulletin. 2024. V.73. N5. P.1417-1425. DOI: 10.1007/s11172-024-4260-4 Scopus OpenAlex
Synthesis of hexaarabinofuranoside bearing the 4-(3-azidopropoxy)phenyl aglycone related to the terminal fragment of polysaccharides of mycobacteria
Russian Chemical Bulletin. 2024. V.73. N5. P.1417-1425. DOI: 10.1007/s11172-024-4260-4 Scopus OpenAlex
Идентификаторы БД:
| Scopus: | 2-s2.0-85196618127 |
| OpenAlex: | W4399899308 |