Electrooxidative cleavage of C1-C2 bonds in acenaphthylene and acenaphthenes

Electrooxidative cleavage of C1-C2 bonds in acenaphthylene and acenaphthenes Full article

Journal

Electrochimica Acta
ISSN: 1873-3859 , E-ISSN: 0013-4686

Output data

Year: 1997, Volume: 42, Number: 13-14, Pages: 1933-1941 Pages count : 9 DOI: 10.1016/s0013-4686(97)85464-3

Authors

Ogibin Y.N. ¹ , Ilovaisky A.I. ¹ , Nikishin G.I. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, 117913 Moscow, Russian Federation

The electrooxidative cleavage of C1C2 bonds in acenaphthylene (1), acenaphthene (6), 1-methoxy-(7), 1,1-dimethoxy- (8), and 1,2-dimethoxyacenaphthene (2) resulting from anodic oxidation of these substrates in MeOH is described. The reaction of 1 involves the intermediate formation of 2, and that of 6 and 7 the formation of intermediates 2 and 8 to give 1,8-naphthalenedicarbaldehyde bis(dimethyl acetal) (3), cyclic dimethyl acetal (4), and 1,1,3-trimethoxy-lH,3H-naphtho[1,8-cd]pyran (5) as major final products.

Ogibin Y.N. , Ilovaisky A.I. , Nikishin G.I.
Electrooxidative cleavage of C1-C2 bonds in acenaphthylene and acenaphthenes
Electrochimica Acta. 1997. V.42. N13-14. P.1933-1941. DOI: 10.1016/s0013-4686(97)85464-3 WOS Scopus OpenAlex

Web of science:	WOS:A1997XA82500002
Scopus:	2-s2.0-0030718112
OpenAlex:	W2950651679

DB	Citing
OpenAlex	10
Scopus	13
Web of science	7