Interaction of SiCl2 with CO2 in Ar matrices

Interaction of SiCl2 with CO2 in Ar matrices Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2021, Volume: 31, Number: 2, Pages: 149-153 Pages count : 5 DOI: 10.1016/j.mencom.2021.03.002

Authors

Boganov Sergey E. ¹ , Promyslov Vladimir M. ¹ , Shangin Pavel G. ¹ , Syroeshkin Mikhail A. ¹ , Egorov Mikhail P. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A 1: 1 photostable complex between dichlorosilylene and CO2 was detected using matrix-isolation FTIR spectroscopy. The photostability can be attributed to the existence of photochemical equilibria between this complex and products of its isomerization, first of all, a complex of dichlorosilanone with CO, which are strongly shifted to the complex. A detailed computational study of the potential energy surface of the SiCl2 + CO2 system was carried out.

Boganov S.E. , Promyslov V.M. , Shangin P.G. , Syroeshkin M.A. , Egorov M.P.
Interaction of SiCl2 with CO2 in Ar matrices
Mendeleev Communications. 2021. V.31. N2. P.149-153. DOI: 10.1016/j.mencom.2021.03.002 WOS Scopus OpenAlex

Web of science:	WOS:000635839800002
Scopus:	2-s2.0-85104990851
OpenAlex:	W3151292302

DB	Citing
OpenAlex	5
Scopus	4
Web of science	3