Synthesis of chiral amino acid derivatives in supercritical carbon dioxide using Rh-PipPhos catalyst

Synthesis of chiral amino acid derivatives in supercritical carbon dioxide using Rh-PipPhos catalyst Full article

Journal

Journal of Supercritical Fluids
ISSN: 1872-8162 , E-ISSN: 0896-8446

Output data

Year: 2009, Volume: 50, Number: 2, Pages: 118-120 Pages count : 3 DOI: 10.1016/j.supflu.2009.05.013

Authors

Lyubimov Sergey E. ¹ , Kuchurov Ilya V. ² , Davankov Vadim A. ¹ , Zlotin Sergei G. ²

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Street 28, 119991 Moscow, Russia.
2	N.D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences Leninsky Prosp. 47 119991 Moscow Russia

PipPhos ligand was used in the asymmetric Rh-catalysed hydrogenation of N-acyldehydroamino acid esters in supercritical carbon dioxide with enantioselectivities attained up to 97%. The catalytic performance is affected greatly by temperature and both hydrogen and total pressures.

Lyubimov S.E. , Kuchurov I.V. , Davankov V.A. , Zlotin S.G.
Synthesis of chiral amino acid derivatives in supercritical carbon dioxide using Rh-PipPhos catalyst
Journal of Supercritical Fluids. 2009. V.50. N2. P.118-120. DOI: 10.1016/j.supflu.2009.05.013 Scopus OpenAlex

Scopus:	2-s2.0-67649392248
OpenAlex:	W2049824289

DB	Citing
OpenAlex	20
Scopus	18