The effect of replacing a 3-O-acetyl group by a 3-O-benzyl group in a methyl 4-O-trityl-β-d-xylopyranoside derivative on the efficiency of 1,2-trans-glycosylation with a d-xylose 1,2-O-(1-cyanoethylidene) derivative Full article
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Carbohydrate Research
ISSN: 1873-426X , E-ISSN: 0008-6215 |
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Output data | Year: 1989, Volume: 191, Number: 1, Pages: 13-19 Pages count : 7 DOI: 10.1016/0008-6215(89)85042-6 | ||
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Abstract:
Replacement of AcO-3 in methyl 2,3-di-O-acetyl-4-O-trityl-β-d-xylopyranoside with a benzyl group greatly increases the 1,2-trans-stereoselectivity of glycosylation with a d-xylopyranose 1,2-O-(1-cyanoethylidene) derivative. Anomerisation of methyl 2-O-benzyl-β-d-xylopyranoside derivatives occurred under the action of triphenylmethylium perchlorate.
Cite:
Nifant'ev N.E.
, Backinowsky L.V.
, Kochetkov N.K.
The effect of replacing a 3-O-acetyl group by a 3-O-benzyl group in a methyl 4-O-trityl-β-d-xylopyranoside derivative on the efficiency of 1,2-trans-glycosylation with a d-xylose 1,2-O-(1-cyanoethylidene) derivative
Carbohydrate Research. 1989. V.191. N1. P.13-19. DOI: 10.1016/0008-6215(89)85042-6 OpenAlex
The effect of replacing a 3-O-acetyl group by a 3-O-benzyl group in a methyl 4-O-trityl-β-d-xylopyranoside derivative on the efficiency of 1,2-trans-glycosylation with a d-xylose 1,2-O-(1-cyanoethylidene) derivative
Carbohydrate Research. 1989. V.191. N1. P.13-19. DOI: 10.1016/0008-6215(89)85042-6 OpenAlex
Identifiers:
OpenAlex: | W2087444856 |
Citing:
DB | Citing |
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OpenAlex | 8 |