A New Synthetic Method for 3-Halocyclopentenes via Thermal Conversion of Cycloadducts of Dihalocarbenes with Dicyclopentadiene

A New Synthetic Method for 3-Halocyclopentenes via Thermal Conversion of Cycloadducts of Dihalocarbenes with Dicyclopentadiene Full article

Journal

Synlett
ISSN: 0936-5214 , E-ISSN: 1437-2096

Output data

Year: 1990, Volume: 1990, Number: 11, Pages: 713-714 Pages count : 2 DOI: 10.1055/s-1990-21223

Authors

Kostitsyn A.B. ¹ , Shulishov E.V. ¹ , Tomilov Yu.V. ¹ , Nefedov O.M. ¹

Affiliations

1	N. D. Zelinksy Institute of Organic Chemistry, Academy of Sciences USSR, Leninsky prospect 47, Moscow B-334, USSR

Vacuum thermolysis of readily available 4,4-dihalotetracyclo [6.2.1.02,7.03,5]undec-9-enes, prepared from the addition of dihalocarbenes to endo-tricyclo[5.2.1.02,6]deca-3,8-diene under phase-transfer catalysis, affords 3-halocyclopentenes in high yield (70-80%).

Kostitsyn A.B. , Shulishov E.V. , Tomilov Y.V. , Nefedov O.M.
A New Synthetic Method for 3-Halocyclopentenes via Thermal Conversion of Cycloadducts of Dihalocarbenes with Dicyclopentadiene
Synlett. 1990. V.1990. N11. P.713-714. DOI: 10.1055/s-1990-21223 Scopus OpenAlex

≡ Scopus:	2-s2.0-0343340948
≡ OpenAlex:	W2953217673