Cathodic isomerization of epoxysulfides -sulfoxides and -sulfones

Cathodic isomerization of epoxysulfides -sulfoxides and -sulfones Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 1991, Volume: 32, Number: 8, Pages: 1099-1102 Pages count : 4 DOI: 10.1016/s0040-4039(00)74498-4

Authors

Niyazymbetov M.E. ¹ , Konyushkin L.D. ¹ , Niyazymbetova Z.I. ¹ , Kalugin V.E. ¹ , Litvinov V.P. ¹ , Petrosyan V.A. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, USSR Academy of Sciences, Leninsky Prospekt 47, Moscow 117913, USSR

It has been established that the electrolysis of 2,3-epoxypropylsulfides, -sulfoxides and -sulfones on Pt or glassy carbon cathodes proceeds via the cleavage of the αCH bond, followed by intramolecular interaction of the α-carbanion with epoxidic ring to give corresponding allylic alcohols in good yields. The electrolysis of 2,3-epoxypropylsulfides, -sulfoxides and -sulfones on Pt or glassy carbon cathodes leads to the formation of corresponding allylic alcohols in good yields.

Niyazymbetov M.E. , Konyushkin L.D. , Niyazymbetova Z.I. , Kalugin V.E. , Litvinov V.P. , Petrosyan V.A.
Cathodic isomerization of epoxysulfides -sulfoxides and -sulfones
Tetrahedron Letters. 1991. V.32. N8. P.1099-1102. DOI: 10.1016/s0040-4039(00)74498-4 WOS Scopus OpenAlex

≡ Web of science:	WOS:A1991EZ57400032
≡ Scopus:	2-s2.0-0026059952
≡ OpenAlex:	W2081682113