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Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane Full article

Journal Synthesis-Stuttgart
ISSN: 1437-210X , E-ISSN: 0039-7881
Output data Year: 1990, Volume: 1990, Number: 03, Pages: 246-248 Pages count : 3 DOI: 10.1055/s-1990-26844
Authors Tomilov Yu.V. 1 , Kostitsyn A.B. 1 , Shulishov E.V. 1 , Nefedov O.M. 1
Affiliations
1 N. D.Zelinsky Institute of Organic Chemistry Academy of Sciences USSR, Leninsky prospect 47, Moscow B-334, USSR

Abstract: (Alkoxymethyl)-, (aminomethyl)-, (2-alkoxyethenyl)-, (2-acetoxyethenyl)-, and (2-siloxyethenyl)cyclopropanes are obtained in high yields by reaction of allyl alcohol or derivatives, allylamines, 1-alkoxy-, 1-acetoxy-, and 1-trimethylsiloxy-1,3-butadienes with diazomethane in dichloromethane/diethyl ether in the presence of bis(benzonitrile)palladium dichloride. Anzeige
Cite: Tomilov Y.V. , Kostitsyn A.B. , Shulishov E.V. , Nefedov O.M.
Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane
Synthesis-Stuttgart. 1990. V.1990. N03. P.246-248. DOI: 10.1055/s-1990-26844 Scopus OpenAlex
Identifiers:
≡ Scopus: 2-s2.0-0000984723
≡ OpenAlex: W2084026589
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