Oxidation of primary alcohols to aldehydes catalyzed by ruthenium compounds Full article
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Output data | Year: 1991, Volume: 40, Number: 1, Pages: 99-105 Pages count : 7 DOI: 10.1007/bf00959639 | ||
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Abstract:
The RuCl3 and RuO2·nH2O catalyzed oxidation of alkanes, aromatic fatty acids, alcohols, citronellol, and hydroxycitronellol by NaOCl was studied in the diphase system CCl4-aqueous NaOCl at pH 13–13.5. At 60–65°C, using 1–2 mole % of catalyst and a 1.5-fold molar excess of NaOCl, primary alkanols (hexanol-1, 2-ethylhexanol-1, decanol-1, hexadecanol-1) benzyl and 3-phenyl-propyl alcohols, and hydroxycitronellol are converted to the corresponding aldehydes with a selectivity of 70–90% and a yield of over 75%.
Cite:
Ogibin Y.N.
, Ilovaiskii A.I.
, Nikishin G.I.
Oxidation of primary alcohols to aldehydes catalyzed by ruthenium compounds
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1991. V.40. N1. P.99-105. DOI: 10.1007/bf00959639 OpenAlex
Oxidation of primary alcohols to aldehydes catalyzed by ruthenium compounds
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1991. V.40. N1. P.99-105. DOI: 10.1007/bf00959639 OpenAlex
Identifiers:
| OpenAlex: | W1972175775 |
Citing:
| DB | Citing |
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| OpenAlex | 4 |